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Nezu, the headmaster of UA Academy, resembles a hybrid of a mouse, a bear, and a rabbit. He is incredibly intelligent, calculating, and far-sighted, a master strategist—he is the one who shapes the academy's policies and designs the students' defenses in crisis situations. Cementoss (Atsuhiro Sako), a modern literature teacher, has a Quirk that allows him to manipulate cement: liquefy it or instantly harden it, creating any structure or barrier. He looks like a living block of concrete and is incredibly versatile in battle—he can attack and defend, yet calmly teaches and explains the material. Ectoplasm, a mathematics teacher, uses his Quirk to create copies of himself; the number of clones depends on his concentration. Serious and collected, in critical situations he can literally "fill" the battlefield with copies of himself to hold back enemies and protect the students. Snipe, a combat instructor and long-range combat specialist, is an excellent marksman and teaches students how to aim at a distance. Calm and methodical, he emphasizes calculation and control of the situation rather than brute force.
Power Loader (Tomoko Shirow) is responsible for the heroes' equipment and costumes, designing gear that helps students use their Quirks more effectively. His Quirk gives him steel fingertips, which helps him manipulate materials and construct parts. He's practical and laconic, but indispensable to the entire academy. Thirteen (Kano Anan) is a search-and-rescue specialist; her Quirk creates miniature black holes capable of sucking in and destroying objects. She teaches the students rescue tactics, navigating rubble, and operating in conditions of limited visibility and destruction. Recovery Girl (Chiyo Shuzenji) isn't a teacher in the traditional sense, but the school medic, but she's crucial for the UA students: her Quirk accelerates regeneration and heals injuries almost instantly. Strict and demanding of discipline, she genuinely cares about the students' health and helps them recover from arduous training and battles.

Among the heroes of the My Hero Academia universe, the following stand out: All Might (Toshinori Yagi) - the legendary number one hero, a symbol of peace and hope, his Quirk "One for All" gives colossal strength and speed, for a long time he was the face of the hero society and Midoriya's mentor; Endeavor (Engie Todoroki) - the number two hero, known for his fire Quirk and perseverance, Shoto's father, has long sought to surpass All Might and leave a strong legacy; Midnight (Nemuri Kayama) - a teacher at UA and a heroine with a Quirk that induces sleep through aroma, charismatic and spectacular, knows how to keep the class under control; Present Mic (Hizashi Yamada) - a teacher and hero, uses his voice and sound waves as weapons, energetic and supports his students; Gran Torino - an experienced mentor, All Might's former teacher, his Quirk is associated with maneuverable flight and powerful kicks, strict but caring; Rumi Usagiyama (Miruko) - a rabbit-like heroine with a Quirk that enhances physical abilities, she is fearless, straightforward, and enjoys danger; Mountain Lady (Yuu Takeyama) - a heroine who can grow to gigantic size, is bright and emotional, and loves attention and spectacle; Mountain Lady - sometimes confused with Mountain Lady, but this is a mistake: in canon, it is Yuu Takeyama who is known as Mountain Lady; also worth mentioning is Nana Shimura - the former bearer of One for All, All Might's mentor, whose philosophy greatly influenced his views. Aizawa (Shota Aizawa), aka Eraserhead, is a teacher at UA and a hero whose Quirk "Erase" disables others' Quirks with a glance; Strict, taciturn, and extremely focused on student safety, he often appears tired from constantly using his powers, but he genuinely cares for Class 1-A. Hawks (Keigo Takami) is a winged hero who can fly and manipulate individual feathers, which can be used as both weapons and reconnaissance tools. He is quick, charismatic, and acts with ease and nonchalance, yet is highly effective in combat and an excellent intelligence gatherer.

Izuku Midoriya received One for All, is goal-oriented and empathetic, has green hair, large eyes, and a thin build; Katsuki Bakugou has an explosive quirk, is ambitious and blunt, but reliable in battle, has tousled blond hair, sharp features, and an intense gaze; Shoto Todoroki uses fire and ice, overcomes internal conflicts, has half white and half black hair, heterochromia (different eyes), and a scar on his face; Ochako Uraraka has the Zero Gravity quirk, is friendly and wants to help people, has short brown hair, round eyes, and a sweet smile; Tenya Iida has jet engines in his legs, is responsible and reasonable, has dark hair, glasses, and an athletic build; Tsuyu Asui, with frog-like abilities, is calm and straightforward, dark green hair in ponytails, large eyes, and frog-like features. Minoru Mineta, who uses sticky balls and is frivolous but useful in combat, is small in stature, has purple curly hair and an expressive face. Momo Yaoyorozu, who creates objects from her body and is intelligent and plans well, has long dark hair, delicate features, and a reserved appearance. Kyoka Jiro, who controls sound and is confident and enjoys rock music, has short dark purple hair, contact earrings, and a daring gaze. Fumikage Tokoyami, who controls shadows that grow stronger in the dark and learns to trust others, has messy black hair and a dark aura, and is often hidden by shadows. Tohru Hagakure, who is invisible and cheerful, enjoys the unexpected. Hanta Sero produces sticky tape, is outgoing and laid-back, has normal dark hair and a relaxed expression; Eijiro Kirishima hardens his body to the point of stone, values ​​loyalty and always protects his friends, has pinkish-red tousled hair, an open smile, and a strong build; Denki Kaminari manipulates electricity, can be unpredictable but is powerful offensively, has spiky blond hair and a relaxed expression; Mezo Shoji, with his many movable arms, copies body parts, is silent and reliable, has elongated features, and an unusual silhouette.